Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols.
نویسندگان
چکیده
Molecular modelling of an iodine(III) phenoxide was used as a starting point in the design of chiral aryl iodide catalysts for stereoselective oxidative dearomatization reactions. Using this approach, catalysts derived from 8-iodotetralone and tartaric acid were constructed and used to synthesize enantioenriched para-quinols from phenols.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 29 شماره
صفحات -
تاریخ انتشار 2013